Multiple Alkylation of Thiophene Derivatives with Simple and Extended Diarylcarbenium Ion Pools

• NOKAMI Toshiki

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Present address: Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University

• WATANABE Takashi

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

• TERAO Kimitada

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

• SOGA Kazuya

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

• OHATA Kousuke

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

• YOSHIDA Jun-ichi

  Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

Abstract

The reactions of thiophene derivatives, bithiophene, and terthiophene with an electrochemically generated diarylcarbenium ion pool afforded multiple alkylation products. Extended diarylcarbenium ion pools afforded dendritic molecules by the multiple alkylation of bithophene and terthiophene.

Journal

• Electrochemistry

  Electrochemistry 81 (5), 399-401, 2013

  The Electrochemical Society of Japan

Keywords

• Diarylcarbenium Ion
• Electrochemical Oxidation
• Thiophene
• Alkylation

Details

• CRID: 1390001206496069120
• NII Article ID: 10031152012
• NII Book ID: AN00151637
• DOI: 10.5796/electrochemistry.81.399
• COI: 1:CAS:528:DC%2BC3sXnslGntLg%3D
• ISSN: 21862451
• ISSN: 13443542
• HANDLE: 2433/187102
• NDL BIB ID: 024456232
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I024456232
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/81/5/81_12-11-E50743/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • IRDB
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Allowed