Preparation of Palladium-loaded Polymer Nanoparticles with Catalytic Activity for Hydrogenation and Suzuki Coupling Reactions

  • Hirokazu Seto
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Takato Morii
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Tamami Yoneda
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Tatsuya Murakami
    Center for Nano Materials and Technology, Japan Advanced Institute of Science and Technology
  • Yu Hoshino
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Yoshiko Miura
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University

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<jats:title>Abstract</jats:title> <jats:p>Palladium-loaded polymer nanoparticles with basic functional groups were prepared. When palladium ions were adsorbed on the polymer nanoparticles, the maximum loading capacity on the nanoparticles depended on the basic functional groups in the particles. The reduced palladium had a nanoscale average diameter. The palladium-loaded polymer nanoparticles exhibited catalytic activity for hydrogenation and Suzuki coupling reactions. The catalytic activity of the nanosized palladium-loaded nanoparticles was higher than that of bulk palladium.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 42 (3), 301-303, 2013-03

    Oxford University Press (OUP)

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