Synthesis and Properties of Disiloxane-bridged Cyclophanes Bearing Heteroaromatics

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  • Shin-ichiro Kato
    Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University
  • Nanae Yamazaki
    Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University
  • Toshihiro Tajima
    Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University
  • Yosuke Nakamura
    Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University

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<jats:title>Abstract</jats:title> <jats:p>Disiloxane-bridged cyclophanes 1–3 bearing heteroaromatics were successfully synthesized. Among them, 3 afforded pronounced excimer fluorescence as well as monomer fluorescence in contrast with 1 and 2. The excimer formation in 3 is accomplished by the flexibility of disiloxane linkages and the relatively long lifetime of the excited singlet state.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 42 (4), 401-403, 2013-03-19

    Oxford University Press (OUP)

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