Heteroleptic Palladium(II) Complexes with Mixed Thiol- and Sulfide-containing Amino Acids: Self-assembly of Novel Heptanuclear Coordination Oligomers

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  • Anzu Yokoi
    Department of Chemistry, Graduate School of Science, Osaka University
  • Nobuto Yoshinari
    Department of Chemistry, Graduate School of Science, Osaka University
  • Takumi Konno
    Department of Chemistry, Graduate School of Science, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>Treatment of a cyclic tripalladium(II) complex, [Pd3(d-pen)3] (d-H2pen: d-penicillamine), with l-methionine (l-Hmet) gave a novel open-chain-type S-bridged heptapalladium(II) complex, [Pd7(d-pen)8(l-met)2]4−, besides a monopalladium(II) complex, [Pd(d-pen)(l-met)]−. A similar reaction using S-methyl-l-cysteine (l-Hsmc) instead of l-Hmet produced an analogous heptapalladium(II) complex, [Pd7(d-pen)8(l-smc)2]4−.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 42 (8), 885-887, 2013-05-31

    Oxford University Press (OUP)

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