Solvent-dependent Assembly of Discrete and Continuous CoCl₂ Adamantane-based Ligand Complexes : Observations by CSI-Mass Spectrometry and X-ray Crystallography Solvent-dependent Assembly of Discrete and Continuous CoCl_2 Adamantane-based Ligand Complexes : Observations by CSI-Mass Spectrometry and X-ray Crystallography

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Abstract

Discrete and continuous coordination structures were obtained in single crystals of CoCl<sub>2</sub> and an adamantane-based bidentate ligand bearing imidazolyl groups, depending on the methanol concentration in a methanol–chloroform mixture. Single-crystal X-ray structure analysis revealed that the metal centers exhibited a tetrahedral geometry in the discrete complex and an octahedral geometry in the continuous metal complex. Conventional analytical methods, including UV-vis and NMR spectroscopy, could not identify those two complexes in solution. In contrast, cold-spray ionization mass spectrometry could detect differences between the discrete complex and the continuous metal complex, and ion peaks due to continuous ligand adducts were found only in the spectrum of the continuous metal complex.

Journal

  • Analytical Sciences

    Analytical Sciences 29(8), 773-776, 2013-08-10

    The Japan Society for Analytical Chemistry

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Codes

  • NII Article ID (NAID)
    10031190630
  • NII NACSIS-CAT ID (NCID)
    AA10500785
  • Text Lang
    ENG
  • Article Type
    SHO
  • ISSN
    09106340
  • NDL Article ID
    024737553
  • NDL Call No.
    Z54-F482
  • Data Source
    CJP  NDL  J-STAGE 
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