Magnesimu-Promoted Reductive Silylatinon and Acylation of Tropone and Tropone Acetal

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Author(s)

Abstract

Magnesium-promoted reductive coupling of chlorotrialkylsilanes and tropone or tropone acetal in DMF, followed by oxidation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone in benzene gives 2-trialkylsilyltropones as the main product, and the reductive coupling of tropone with acid anhydrides under similar reaction conditions yields benzene derivatives after ring contraction.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 86(10), 1183-1189, 2013-10-15

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10031201274
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    024925307
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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