Asymmetric Conjugate Addition of Malonates to Enones Using Perfluorobutanesulfonamide Organocatalyst

• Yuji Kamito

  Gifu Pharmaceutical University

• Akira Masuda

  Gifu Pharmaceutical University

• Hiroki Yuasa

  Gifu Pharmaceutical University

• Norihiro Tada

  Gifu Pharmaceutical University

• Akichika Itoh

  Gifu Pharmaceutical University

• Yuji Koseki

  Tokyo University of Pharmacy and Life Sciences

• Tsuyoshi Miura

  Tokyo University of Pharmacy and Life Sciences

抄録

Perfluorobutanesulfonamide organocatalyst 4 efficiently promotes asymmetric conjugate additions of malonates to α,β-unsaturated ketones to afford the corresponding adducts with excellent enantioselectivities (up to 99% ee).

収録刊行物

• Chemistry Letters

  Chemistry Letters 42 (10), 1151-1153, 2013-10

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644035557120
• NII論文ID: 10031201292
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.130575
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/42/10/1151/55636023/cl.130575.pdf
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