Effects of MgCl<sub>2</sub> Addition on Struvite Precipitation and Ammonia Emission during the Early Stage of Composting

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  • 塩化マグネシウムの添加が堆肥化早期のstruvite生成とアンモニア揮散とに及ぼす影響
  • エンカ マグネシウム ノ テンカ ガ タイヒカ ソウキ ノ struvite セイセイ ト アンモニアキサン ト ニ オヨボス エイキョウ

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Abstract

The effects of MgCl2 addition to composting material on struvite precipitation and ammonia emission were investigated. Beef cattle manure was used as the composting material and the 15-day composting process was carried out in a small-size reactor. When the rate of MgCl2 addition was increased, the pH of the initial material decreased and the electrical conductivity increased. In addition, the degradation rate of volatile matter decreased to 63 % of that without addition of MgCl2 when the addition rate was 0.4 mole per kg of initial dry manure (mol kgDM0-1). An increase in struvite nitrogen was observed after MgCl2 addition at 0.03 mol kgDM0-1 (MgCl2 additon: 0.1 mol kgDM0-1) ~0.07 (MgCl2 additon: 0.4 mol kgDM0-1), and the utilization rate of Mg from additional MgCl2 for struvite precipitation was calculated to be 34-16 %. Ammonia emission after 0.4 mol kgDM0-1 MgCl2 addition decreased to 70 % of that without MgCl2 addition. These results suggest that, following the addition of MgCl2 to composting material pH reduction had a greater effect on the reduction of ammonia emission than did the increase in struvite precipitation.

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