2B04 Unprecedented Novel Mesophase M (Pa2_1) Arisen from Biomembrane-like Bilayer Structure of VO (salen)- based Complexes

DOI
  • Sugibayashia Makiko
    Department of Functional Polymer Science, Faculty of Textile Science & Technology, Shinshu University
  • Ohta Kazuchika
    Department of Functional Polymer Science, Faculty of Textile Science & Technology, Shinshu University
  • Abe Yuriko
    Department of Chemistry, Faculty of Science, Nara Women's University
  • Nakabayashi Kyoko
    Department of Chemistry, Faculty of Science, Nara Women's University
  • Matsukawa Nahoko
    Department of Chemistry, Faculty of Science, Nara Women's University
  • Iida Masayasu
    Department of Chemistry, Faculty of Science, Nara Women's University
  • Tanase Tomoaki
    Department of Chemistry, Faculty of Science, Nara Women's University

Bibliographic Information

Other Title
  • 2B04 VO(salen)系金属錯体の生体膜様二層構造から誘起された前例のない新規なM(Pa2_1)液晶相(化学・材料)

Abstract

A series of V (IV) complexes with 4-substituted salen ligands formulated as [VO ((4-C_nH_<2n+1>O)_2salen)] (n=12, 14, 16, 18, and 20), which formed novel biomembrane-like bilayer crystal structure without the linear chain via the V=O units, showed a novel bilayer mesophase having unprecedented symmetry Pa2_1 in the layers.

Journal

Details 詳細情報について

  • CRID
    1390001205686884864
  • NII Article ID
    110001482240
  • DOI
    10.11538/ekitou.2003.0_157
  • ISSN
    24325988
    18803490
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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