2,3-<i>O</i>-シクロヘキシリデン-D-グリセルアルデヒドから (-)-<i>ent</i>-アルトラクトン, (+)-7a-<i>epi</i>-アルトラクトン, (-)-<i>ent</i>-イソアルトラクトンおよび (-)-7a-<i>epi</i>-イソアルトラクトンの合成

• 平舘 彰

  Department of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University

• 清田 洋正

  Department of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University

• 折谷 隆之

  Department of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University

書誌事項

タイトル別名

• Synthesis of (-)-<i>ent</i>-Altholactone, (+)-7a-<i>epi</i>-Altholactone, (-)-<i>ent</i>-Isoaltholactone and (-)-7a-<i>epi</i>-Isoaltholactone from 2, 3-<i>O</i>-Cyclohexylidene-D-glyceraldehyde
• Synthesis of (-)-ent-Altholactone, (+)-7a-epi-Altholactone, (-)-ent-Isoaltholactone and (-)-7a-epi-Isoaltholactone from 2,3-O-Cyclohexylidene-D-glyceraldehyde

抄録

Synthesis of the diastereomers of (+)-altholactone, an antitumor acetogenin from various Goniothalamus species, was achieved. Four isomers including 3a, 7a-trans-fused analogs were synthesized from 2, 3-O-cyclohexylidene-D-glyceraldehyde via twice separation of diastereomers.

収録刊行物

• 日本農薬学会誌（Ｊｏｕｒｎａｌ　ｏｆ　Ｐｅｓｔｉｃｉｄｅ　Ｓｃｉｅｎｃｅ）

  日本農薬学会誌（Ｊｏｕｒｎａｌ　ｏｆ　Ｐｅｓｔｉｃｉｄｅ　Ｓｃｉｅｎｃｅ） 26 (4), 361-365, 2001

  日本農薬学会

キーワード

• altholactone
• Isoaltholactone
• goniothalenol
• total synthesis

詳細情報

• CRID: 1390282680187633920
• NII論文ID: 110001713255
• NII書誌ID: AN00196227
• ISSN: 03851559
• ISSN: 13490923
• ISSN: 1348589X
• DOI: 10.1584/jpestics.26.361
• NDL書誌ID: 5981806
• Web Site: https://agriknowledge.affrc.go.jp/RN/2030640602
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5981806
• Web Site: http://www.jstage.jst.go.jp/article/jpestics1975/26/4/26_4_361/_pdf
• Web Site: http://dl.ndl.go.jp/info:ndljp/pid/10877184
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