Valence-Band Structures of Quasi-One-Dimensional Crystals C_5H_<10>NH_2PbX_3 [X = I, Br]

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Abstract

X-ray and ultra-violet photoemission spectra have been measured to study the valence-band structures of piperidinium trihaloplumbates C<FONT SIZE="-1"><SUB>5</SUB></FONT>H<FONT SIZE="-1"><SUB>10</SUB></FONT>NH<FONT SIZE="-1"><SUB>2</SUB></FONT>PbX<FONT SIZE="-1"><SUB>3</SUB></FONT> [X = I, Br], which have natural nano-scale one-dimensional structures. The valence-band spectra of lead halides, which have the three-dimensional structures, are also reported for comparison. The partial densities of states related to the constituent ions and molecules were obtained with the comparison between the XPS and UPS. Empirical LCAO calculations were also carried out to analyze the experimental results. The quantum-well-like electronic structure in C<FONT SIZE="-1"><SUB>5</SUB></FONT>H<FONT SIZE="-1"><SUB>10</SUB></FONT>NH<FONT SIZE="-1"><SUB>2</SUB></FONT>PbX<FONT SIZE="-1"><SUB>3</SUB></FONT> [X = I, Br] is proposed.

Journal

  • Journal of the Physical Society of Japan

    Journal of the Physical Society of Japan 71(11), 2730-2735, 2002-11-15

    The Physical Society of Japan (JPS)

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Codes

  • NII Article ID (NAID)
    110001954130
  • NII NACSIS-CAT ID (NCID)
    AA00704814
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00319015
  • NDL Article ID
    6359512
  • NDL Source Classification
    ZM35(科学技術--物理学)
  • NDL Call No.
    Z53-A404
  • Data Source
    CJP  NDL  NII-ELS  J-STAGE 
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