Valence-Band Structures of Quasi-One-Dimensional Crystals C<FONT SIZE="-1"><SUB>5</SUB></FONT>H<FONT SIZE="-1"><SUB>10</SUB></FONT>NH<FONT SIZE="-1"><SUB>2</SUB></FONT>PbX<FONT SIZE="-1"><SUB>3</SUB></FONT> [X = I, Br]
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- Azuma Junpei
- Department of Physics, Kyoto University, Sakyo, Kyoto 606-8502
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- Tanaka Koichiro
- Department of Physics, Kyoto University, Sakyo, Kyoto 606-8502
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- Kamada Masao
- UVSOR Facility, Institute for Molecular Science, Myodaiji, Okazaki 444-8585
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- Kan'no Ken-ichi
- Department of Material Science and Chemistry, Wakayama University, Sakaedani, Wakayama 640-8510
Bibliographic Information
- Other Title
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- Valence-Band Structures of Quasi-One-Dimensional Crystals C5H10NH2PbX3[X=I, Br]
- Valence-Band Structures of Quasi-One-Dimensional Crystals C<sub>5</sub>H<sub>10</sub>NH<sub>2</sub>PbX<sub>3</sub>[X = I, Br]
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Abstract
X-ray and ultra-violet photoemission spectra have been measured to study the valence-band structures of piperidinium trihaloplumbates C5H10NH2PbX3 [X = I, Br], which have natural nano-scale one-dimensional structures. The valence-band spectra of lead halides, which have the three-dimensional structures, are also reported for comparison. The partial densities of states related to the constituent ions and molecules were obtained with the comparison between the XPS and UPS. Empirical LCAO calculations were also carried out to analyze the experimental results. The quantum-well-like electronic structure in C5H10NH2PbX3 [X = I, Br] is proposed.
Journal
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 71 (11), 2730-2735, 2002
THE PHYSICAL SOCIETY OF JAPAN
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Details 詳細情報について
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- CRID
- 1390282679160654336
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- NII Article ID
- 210000103961
- 110001954130
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- NII Book ID
- AA00704814
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- BIBCODE
- 2002JPSJ...71.2730A
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- ISSN
- 13474073
- 00319015
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- NDL BIB ID
- 6359512
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed