Experimental Elucidation: Microscopic Mechanism of Resonant X-Ray Scattering in Manganite Films

  • Ohsumi Hiroyuki
    Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization
  • Murakami Yoichi
    Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization Core Research for Evolutional Science and Technology (CREST) Synchrotron Radiation Research Center, Japan Atomic Energy Research Institute (SPring-8)
  • Kiyama Takashi
    Department of Physics, Chiba University
  • Nakao Hironori
    Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization Core Research for Evolutional Science and Technology (CREST)
  • Kubota Masato
    Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization
  • Wakabayashi Yusuke
    Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization Department of Physics, Keio University
  • Konishi Yoshinori
    Joint Research Center for Atom Technology (JRCAT)
  • Izumi Makoto
    Joint Research Center for Atom Technology (JRCAT)
  • Kawasaki Masashi
    Correlated Electron Research Center (CERC), AIST Department of Innovative and Engineered Materials, Tokyo Institute of Technology
  • Tokura Yoshinori
    Correlated Electron Research Center (CERC), AIST Department of Applied Physics, University of Tokyo

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Resonant X-ray scattering experiments have been performed on perovskite manganite La0.5Sr0.5MnO3 thin films, which are grown on three distinct perovskite substrates with a coherent epitaxial strain and have a forced ferro-type orbital ordering of Mn 3d orbitals. Using an interference technique, we have successfully observed the resonant X-ray scattering signal from the system having the ferro-type orbital ordering and also revealed the energy scheme of Mn 4p bands. For the forced ferro-type orbital ordering system, the present results evidence that the resonant X-ray scattering signal originates from the band structure effect due to the Jahn–Teller distortion of a MnO6 octahedron, and not from the Coulomb interaction between 3d and 4p electrons.

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