Critical Behaviour of Specific Heat in Ferroelectric K2ZnCl4 and (NH4)2BeF4 at Normal-Incommensurate Phase Transition

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  • Critical Behaviour of Specific Heat in Ferroelectric K<SUB>2</SUB>ZnCl<SUB>4</SUB> and (NH<SUB>4</SUB>)<SUB>2</SUB>BeF<SUB>4</SUB> at Normal-Incommensurate Phase Transition
  • Critical Behaviour of Specific Heat in

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Measurements of specific heat were carried out on structurally incommensurate ferroelectrics K2ZnCl4 and (NH4)2BeF4 over a wide temperature region with an AC calorimetric technique. Critical indices α associated with the normal-incommensurate phase transition are obtained as 0.12±0.02 for K2ZnCl4 and 0.18±0.02 for (NH4)2BeF4. These values do not agree with that in the 3d XY-model proposed by Bruce and Cowley, and are rather comparable with α=0.125 for the 3d Ising-model. A crossover from a logarithmic behaviour to a power-law behaviour was found at reduced temperatures tcr=1×10−3 for K2ZnCl4 and 5×10−3 for (NH4)2BeF4, respectively.

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