Neutron Diffraction Study on MnPS3 and FePS3

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  • Neutron Diffraction Study on MnPS<SUB>3</SUB> and FePS<SUB>3</SUB>
  • Neutron Diffraction Study on MnPS3 and

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Neutron diffraction study on the layer compounds MnPS3 and FePS3 reveals a collinear antiferromagnetic order, respectively, below TN=78 K and 120 K with the corresponding wave vectors k=[000] and (Remark: Graphics omitted.), the magnetic moments pointing to the direction perpendicular to the layer planes for both cases. The intralayer exchange parameters between first (J1), second (J2) and third nearest neighbors (J3) are all antiferromagnetic for MnPS3, whereas for FePS3 J1 is ferromagnetic and J2 and J3 are antiferromagnetic, all of which have the same sign as those for the respective selenium compounds, but the absolute values are a bit larger in the sulfides than in the selenides.

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