Calorimetric Study on Metal-Insulator Transition of Quasi-One-Dimensional BaVS<sub><b>3</b></sub>

  • Imai Hideto
    Department of Materials Science and Engineering, Kyoto University, Kyoto 606–01
  • Wada Hirofumi
    Department of Materials Science and Engineering, Kyoto University, Kyoto 606–01
  • Shiga Masayuki
    Department of Materials Science and Engineering, Kyoto University, Kyoto 606–01

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  • Calorimetric Study on Metal-Insulator Transition of Quasi-One-Dimensional BaVS3.
  • Calorimetric Study on Metal-Insulator T

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The specific heat of BaVS3, which undergoes a metal-insulator transition at TMI=70 K, was measured in the temperature range of 1.4 K to 300 K. A specific heat anomaly was found at TMI.The entropy change associated with this anomaly is estimated to be 4.7 J/K mol, which is close to R ln 2, the expected magnetic entropy for S=1/2 spins of V atoms. At low temperatures, a T-linear contribution of the specific heat with an apparent γ value of 15.7 mJ/K2 mol was observed in spiteof the absence of conduction electrons. This T-linear contribution may be attributed to spin wave excitations for a one-dimensional antiferromagnet.

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