Magnetic Properties of 3d Transition Element Intercalated Compounds M_{<i><i>x</i></i>}TiSe_<b>2</b>

• Tazuke Yuuichi

  Faculty of Engineering, Ibaraki University, Hitachi, Ibaraki 316

• Takeyama Tomohisa

  Faculty of Engineering, Ibaraki University, Hitachi, Ibaraki 316

書誌事項

タイトル別名

• Magnetic Properties of 3d Transition Element Intercalated Compounds MxTiSe2.
• Magnetic Properties of 3d Transition El

抄録

Polycrystalline samples of M_xTiSe₂ with M=V, Cr, Mn, Fe, Co, Ni and Cu were prepared. All the compounds showed paramagnetic behavior at 4.2, K≤ T≤ 300, K. Effective paramagnetic moment μ _eff of all the M-atoms are much smaller than ionic values, suggesting that the M-states are strongly hybridized with the TiSe₂-band. Cr, Mn, Fe and Co may be in the high-spin states. The μ _eff-data are compared with those of T_yTiS₂ with T=V, Mn, Fe, Co, Ni and Cu in our previous studies and with the band calculation results of Motizuki et al., and discussions are done about the electronic states of T- and M-atoms. It is suggested that the S-3p states are hardly hybridized and the Se-3p states are slightly hybridized with a Ti-3dε non-bonding band.

収録刊行物

• Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ

  Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ 66 (3), 827-830, 1997

  一般社団法人 日本物理学会

キーワード

• intercalation compound
• M<SUB>x</SUB>TiSe<SUB>2</SUB> (M=V
• Cr
• Mn
• Fe
• Co
• Ni
• Cu)
• T<SUB>y</SUB>TiS<SUB>2</SUB> (T=V
• paramagnetism
• effective paramagnetic moment
• hybridization

詳細情報

• CRID: 1390282679156687360
• NII論文ID: 210000100676
• NII論文ID: 110001970315
• NII書誌ID: AA00704814
• DOI: 10.1143/jpsj.66.827
• BIBCODE: 1997JPSJ...66..827T
• ISSN: 13474073
• ISSN: 00319015
• NDL書誌ID: 4187933
• Web Site: http://id.ndl.go.jp/bib/4187933
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4187933
• Web Site: http://journals.jps.jp/doi/pdf/10.1143/JPSJ.66.827
• 本文言語コード: en
• データソース種別:
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  • NDL
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  • CiNii Articles
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