Orbital Frustration and Resonating Valence Bond State in the Spin-1/2 Triangular Lattice LiNiO<sub><b> 2</b></sub>

  • Kitaoka Yoshio
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531 CREST, Japan Science and Technology Corporation (JST)
  • Kobayashi Tatsuo
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531 Research Center for Materials Science at Extreme Conditions, OsakaUniversity, Toyonaka, Osaka 560–8531 CREST, Japan Science and Technology Corporation (JST)
  • Koda Akihiro
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531 Research Center for Materials Science at Extreme Conditions, OsakaUniversity, Toyonaka, Osaka 560–8531
  • Wakabayashi Hayato
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531
  • Niino Yoshihiro
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531
  • Yamakage Hirokazu
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531
  • Taguchi Shinichiro
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531
  • Amaya Kiichi
    Department of Physical Science, Graduate School of EngineeringScience, Osaka University, Toyonaka, Osaka 560–8531 CREST, Japan Science and Technology Corporation (JST)
  • Yamaura Kazunari
    Institute for Chemical Research, Kyoto University, Uji, Kyoto–fu 611–0011
  • Takano Mikio
    Institute for Chemical Research, Kyoto University, Uji, Kyoto–fu 611–0011 CREST, Japan Science and Technology Corporation (JST)
  • Hirano Atushi
    Department of Chemistry, Faculty of Science, Kobe University, Kobe, Hyogo 657–8501
  • Kanno Ryoji
    Department of Chemistry, Faculty of Science, Kobe University, Kobe, Hyogo 657–8501

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タイトル別名
  • Orbital Frustration and Resonating Valence Bond State in the Spin-1/2 Triangular Lattice LiNiO2.
  • Orbital Frustration and Resonating Vale

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From the 7Li nuclear magnetic resonance (NMR) and specific heatmeasurements of LiNiO2, consisting of a spin-1/2 triangular lattice, itis demonstrated that the previously suggested spin-glass-like freezingbelow Tsg=8, K, which is caused by defects of Li ions, is not the trueground state, but rather a quantum disordered state is realized without aspin gap. This state is characterized by power-law behavior of thetemperature dependence of the specific heat below 0.5, K. A spin-liquidstate with short-range ferromagnetic correlations is suggested from newinsight into the frustration of orbital ordering for doubly degeneratee_g shells in the triangular lattice.

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