Double q Condensation at V-Point on the Phase Transition of K3D(SO4)2.

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  • Double q Condensation at V Point on the
  • Double<i>q</i>Condensation at V-Point on the Phase Transition of K<sub>3</sub>D(SO<sub>4</sub>)<sub>2</sub>

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Abstract

Low temperature Weissenberg photograph of K3D(SO4)2(-- 92\associated with the phase transition. Three type superlattice reflectionswere found below Tc (77.5, K), ones at(0 {1em}± 1/2 {1em}± 1/2) V-point and others atlattice points (Z and Γ-points) violating the extinctionrule of the space group A2/a of the high temperature phase. Thediffuse scattering was observed above Tc around(0 {1em}1/2 {1em}1/2) type reflection. It was revealedthat the double q condensation occurred at the V-point and ones atthe Z and Γ-points were secondary order parameters. Theunit cell of the low temperature phase was determined asa× 2b× 2c, and the space group was A2.

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