Transformation between Monovalent and Divalent Ionic Solids : An Ionic(I)-Ionic(II) Phase Transition in a Biferrocene-F_1TCNQ Charge-Transfer Complex

Search this Article

Author(s)

Abstract

An "ionic(I)-ionic(II)" charge-transfer transition has been observed in a new molecular solid composed of dineopentylbiferrocene (D) and fluorotetracyanoquinodimethane (A). The material is a monovalent solid (D^+A_3^-) at room temperature and changes to a divalent solid (D^<2+>A_3^<2->) at low temperatures, in association with a broad first-order phase transition at around 120K.

Journal

  • Journal of the Physical Society of Japan

    Journal of the Physical Society of Japan 74(8), 2214-2216, 2005-08-15

    The Physical Society of Japan (JPS)

References:  16

  • <no title>

    HENDRICKSON D. N.

    Mixed Valency Systems : Applications in Chemistry, Physics, and Biology, 1991

    Cited by (1)

  • <no title>

    COWAN D. O.

    Acc. Chem. Res. 6, 1, 1973

    Cited by (1)

  • <no title>

    MOCHIDA T.

    Bull. Chem. Soc. Jpn. 76, 2321, 2003

    Cited by (1)

  • <no title>

    GUTLICH P. ed.

    Spin Crossover in Transition Metal Compounds, 2004

    Cited by (1)

  • <no title>

    MORRISON W. H.

    Inorg. Chem. 12, 1998, 1973

    Cited by (1)

  • <no title>

    GUTLICH P.

    Mossbauer Spectroscopy and Transition Metal Chemistry, 1978

    Cited by (1)

  • <no title>

    STANG S. L.

    J. Chem. Soc., Dalton Trans., 1998

    Cited by (1)

  • <no title>

    SHIMAHARA H.

    J. Phys. Soc. Jpn. 74, 823, 2005

    Cited by (1)

  • <no title>

    TORRANCE J. B.

    Phys. Rev. Lett. 46, 253, 1981

    Cited by (19)

  • <no title>

    MITANI T.

    Phys. Rev. B 35, 427, 1987

    Cited by (4)

  • <no title>

    HORIUCHI S.

    Science 299, 229, 2003

    Cited by (8)

  • <no title>

    COLLET E.

    Science 300, 612, 2003

    Cited by (19)

  • <no title>

    SANO H.

    Hyperfine Int. 53, 97, 1990

    Cited by (1)

  • <no title>

    FUJITA W.

    Science 286, 261, 1999

    Cited by (11)

  • <no title>

    ITKIS M. E.

    Science 296, 1443, 2002

    Cited by (6)

  • <no title>

    KISTENMACHER T. J.

    Acta Crystallogr., Sect. B 38, 1193, 1982

    Cited by (7)

Codes

  • NII Article ID (NAID)
    110001979694
  • NII NACSIS-CAT ID (NCID)
    AA00704814
  • Text Lang
    ENG
  • Article Type
    SHO
  • ISSN
    00319015
  • NDL Article ID
    7394769
  • NDL Source Classification
    ZM35(科学技術--物理学)
  • NDL Call No.
    Z53-A404
  • Data Source
    CJP  NDL  NII-ELS 
Page Top