Transformation between Monovalent and Divalent Ionic Solids: An Ionic(I)–Ionic(II) Phase Transition in a Biferrocene–F₁TCNQ Charge-Transfer Complex

• Mochida Tomoyuki

  Department of Chemistry, Faculty of Science, Toho University

• Takazawa Kousuke

  Department of Chemistry, Faculty of Science, Toho University

• Takahashi Masashi

  Department of Chemistry, Faculty of Science, Toho University

• Takeda Masuo

  Department of Chemistry, Faculty of Science, Toho University

• Nishio Yutaka

  Department of Physics, Faculty of Science, Toho University

• Sato Michiko

  Department of Physics, Faculty of Science, Toho University

• Kajita Koji

  Department of Physics, Faculty of Science, Toho University

• Mori Hatsumi

  Institute for Solid State Physics, The University of Tokyo

• M. Matsushita Michio

  Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo

• Sugawara Tadashi

  Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo

書誌事項

タイトル別名

• Transformation between Monovalent and Divalent Ionic Solids: An Ionic(I)-Ionic(II) Phase Transition in a Biferrocene-F1TCNQ Charge-Transfer Complex
• Transformation between Monovalent and Divalent Ionic Solids An Ionic 1 Ionic 2 Phase Transition in a Biferrocene F1TCNQ Charge Transfer Complex

抄録

An “ionic(I)–ionic(II)” charge-transfer transition has been observed in a new molecular solid composed of dineopentylbiferrocene (D) and fluorotetracyanoquinodimethane (A). The material is a monovalent solid (D⁺A₃⁻) at room temperature and changes to a divalent solid (D²⁺A₃²⁻) at low temperatures, in association with a broad first-order phase transition at around 120 K.

収録刊行物

• Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ

  Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ 74 (8), 2214-2216, 2005

  一般社団法人 日本物理学会

キーワード

• biferrocene
• F<SUB>1</SUB>-TCNQ
• charge-transfer complex
• phase transition
• valence transition

詳細情報

• CRID: 1390282679164707328
• NII論文ID: 210000105583
• NII論文ID: 110001979694
• NII論文ID: 130004539348
• NII書誌ID: AA00704814
• DOI: 10.1143/jpsj.74.2214
• BIBCODE: 2005JPSJ...74.2214M
• COI: 1:CAS:528:DC%2BD2MXhtFWisLrK
• ISSN: 13474073
• ISSN: 00319015
• NDL書誌ID: 7394769
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7394769
• Web Site: https://journals.jps.jp/doi/pdf/10.1143/JPSJ.74.2214
• 本文言語コード: en
• データソース種別:
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  • NDL
  • Crossref
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  • KAKEN
• 抄録ライセンスフラグ: 使用不可