スピネル・カーボン系クリンカーの作製

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  • Formation of Spinel-Carbon Composite Clinker.

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A spinel-carbon clinker has been prepared through a two-step heating process of MgO-Al compact in CO atmosphere. Al partially changes into intermediate phases during low temperature heating step. The phases further react with MgO and CO during high temperature heating step to form spinel and carbon. The precipitated carbon phase is almost amorphous and finely distributed throughout the spinel phase. Because of its low degree of crystallinity, the precipitated carbon shows an oxidation resistance lower than graphite. At higher temperatures, the effect of heating in CO gas on the clinker is negligible, but heating in Ar gas strongly reduces the clinker.

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