書誌事項
- タイトル別名
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- Structural Studies on Alkaline Earth Vanadate Glasses (Part 1)
- アルカリ ドルイ キンゾク バナジンサンエン ガラス ノ コウゾウ ケンキュウ
- IR Spectroscopic Study
- 赤外分光法による研究
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抄録
The structure of alkaline earth vanadate glasses of the compositions, xMO⋅(100-x)V2O5 (M=Mg, Ca, Sr, Ba, x=30, 40, 45, 50, 55), has been investigated by means of IR spectroscopy with reference to various crystalline alkaline earth vanadates structurally known. It is found that the structure of alkaline earth vanadate glasses is very similar to each other and mainly consists of VO4-tetrahedra which form either (VO3)n-sin-gle chains as found in Sr(VO3)2 and Ba(VO3)2 crystals or the three dimensional arrangement of the cornersharing branched VO4-tetrahedral groups as found in molten and amorphous V2O5. It is stressed that the glass network of the V2O5-rich glasses, 30MO⋅70V2O5, also mainly consists of VO4-tetrahedra.
収録刊行物
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- Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
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Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) 102 (1186), 522-529, 1994
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390001205277296128
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- NII論文ID
- 110002290606
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- NII書誌ID
- AN10040326
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- ISSN
- 18821022
- 09145400
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- NDL書誌ID
- 3880079
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- データソース種別
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- JaLC
- NDL
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