新しい有機ケイ素前駆体からのケイ素を含むアモルファス炭素の生成

書誌事項

タイトル別名
  • Formation of Amorphous Carbon Containing Silicon from a New Organosilicon Precursor
  • Formation of Amorphous Carbon Containin

この論文をさがす

抄録

Amorphous carbon in membrane form containing a small amount of silicon uniformly in the structure was prepared by firing a new organosilicon precursor, poly (phenylsilylene)-ethynylene-1, 3-phenylene-ethynylene (MSP). The pyrolyzed products look like glassy carbon. The cross-linking processes before pyrolysis were effective to keep its shape during the heat treatment and were influenced by oxygen in an ambient atmosphere during cross-linking processes. The oxygen introduced into the precursor enhanced the cross-linking but decreased the residual weight after the pyrolysis. In the pyrolyzed products, silicon atoms appeared to distribute uniformly from the outer surface to interior core. The structure of the products was amorphous, but β-SiC precipitated beyond 1873K.

収録刊行物

被引用文献 (4)*注記

もっと見る

参考文献 (20)*注記

もっと見る

詳細情報 詳細情報について

問題の指摘

ページトップへ