金属添加炭素試料からのクラスター生成と化学反応

• 河野 正道

• 井上 修平

• 丸山 茂夫

書誌事項

タイトル別名

• Mass Spectroscopy and Reaction Studies of Laser-Vaporized Clusters from Metal-Doped Carbon Materials
• キンゾク テンカ タンソ シリョウ カラ ノ クラスター セイセイ ト カガク ハンノウ

抄録

Metal-carbon binary clusters are believed to be important precursor clusters both for single-walled carbon nanotubes (SWNTs) and endohedral metallofullerene. Metal-carbon binary clusters (MC_n M=La, Ni or Co) and carbon clusters (C_n) were generated with a pulsed laser-vaporization supersonic-expansion cluster beam source directly connected to the FT-ICR (Fourier transform ion cyclotron resonance) mass spectrometer, and chemical reaction of MC_n^- and C_n^- with nitric oxide was studied. Depending on the metal element, the generation efficiency and the reactivity of metal-carbon binary clusters were completely different. LaC_n^- (n = even, n>36) was much less reactive to NO than pure carbon clusters, while MC_n^- (M = Ni or Co) was much more reactive than pure carbon clusters. It was speculated that LaC_n^- (n=even, n>36) had a fullerene-like cage structure with a metal atom inside, and that MC_n^- (M = Ni or Co) had an imperfect cage structure where a metal atom preferentially attached to the imperfect site.

収録刊行物

• 日本機械学会論文集Ｂ編

  日本機械学会論文集Ｂ編 69 (684), 1886-1892, 2003

  一般社団法人 日本機械学会

キーワード

• Nanotube

詳細情報

• CRID: 1390282681238428544
• NII論文ID: 130004224968
• NII論文ID: 110002388281
• NII書誌ID: AN00187441
• DOI: 10.1299/kikaib.69.1886
• ISSN: 18848346
• ISSN: 03875016
• NDL書誌ID: 6688590
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I6688590
• Web Site: http://www.jstage.jst.go.jp/article/kikaib1979/69/684/69_684_1886/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可