コウジ酸を用いるフローインジェクション法による金の蛍光定量
-
- 伊東 琢史
- 静岡大学工業短期大学部
書誌事項
- タイトル別名
-
- Flow-injection spectrofluorometric determination of gold with kojic acid.
- コウジサン オ モチイル フロー インジェクションホウ ニ ヨル キン ノ ケ
この論文をさがす
抄録
A flow-injection spectrofluorometric method was devised for the determination of gold (III) based on the fluorescent oxidized product of kojic acid. The maximum wavelengths of the excitation and emission spectra of the oxidized product are 375 and 495nm, respectively. The carrier solution (0.1M sodium chloride) and buffer solution (pH 7.5) containing 8×10-3 M kojic acid were each pumped at 1.5ml min-1. The length of the reaction coil was 1m. The present method allows the determination of 110μg ml-1 of gold (III) based on 100μl injection volume. The relative standard deviation of 1.2% (n = 9) was obtained at 3μg ml-1 of gold ( III ). The sample throughput was about 20h-1. Palladium does not interfere with up to 50-fold amounts under masking with nitrilotriacetic acid.
収録刊行物
-
- 分析化学
-
分析化学 44 (4), 297-300, 1995
公益社団法人 日本分析化学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390282679029711872
-
- NII論文ID
- 110002906932
-
- NII書誌ID
- AN00222633
-
- NDL書誌ID
- 3614691
-
- ISSN
- 05251931
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- NDL-Digital
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可