Biomimetic Oxidation of Curcumin with Hydrogen Peroxide Catalyzed by 5,10,15,20-Tetraarylporphyrinatoiron(III) Chlorides in Dichloromethane

• Chauhan Shive Murat Singh

  Department of Chemistry, University of Delhi

• Kandadai Appan Srinivas

  Department of Chemistry, University of Delhi

• Jain Nidhi

  Department of Chemistry, University of Delhi

• Kumar Anil

  Department of Chemistry, University of Delhi

書誌事項

タイトル別名

• Biomimetic Oxidation of Curcumin with Hydrogen Peroxide Catalyzed by 5 10 15 20 Tetraarylporphyrinatoiron 3 Chlorides in Dichloromethane

抄録

The biomimetic oxidation of curcumin, a main turmeric pigment with hydrogen peroxide catalyzed by different 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides [TAPFe(III)Cl] in dichloromethane has been studied to give a C–C coupled curcumin dimer in 40—70% yield. The structure of the dimer has been elucidated by ¹H-, ¹³C-NMR, IR and FAB-Mass spectroscopic data.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 51 (11), 1345-1347, 2003

  公益社団法人 日本薬学会

キーワード

• biomimetic oxidation
• curcumin
• 5,10,15,20-tetraarylporphyrinatoiron(III) chloride
• hydrogen peroxide
• curcumin dimer

詳細情報

• CRID: 1390001204166534272
• NII論文ID: 110003615220
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.51.1345
• ISSN: 13475223
• ISSN: 00092363
• NDL書誌ID: 6723490
• PubMed: 14600390
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I6723490
• Web Site: http://www.jstage.jst.go.jp/article/cpb/51/11/51_11_1345/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可