Tetrodotoxin. VII. On the structure of tetrodotoxin and its derivatives

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  • Tetrodotoxin. VII. On the Structures of Tetrodotoxin and its Derivatives

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The structures of both tetrodonic acid hydrobromide and 6, 11-diacetylanhydrotetrodotoxin hydroiodide were established by chemical and X-ray crystallographical research. Based upon structures of both these salts and upon other chemical information, we determined that tetrodotoxin and anhydrotetrodotoxin have zwitterionic hemilactal structures.

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