Electron Spin Resonance Studies of Photo-sensitized Decomposition of Methyl Alcohol in the Presence of p-Benzoquinone.

• 神谷 護

• 畑野 研一郎

• 管 孝男

抄録

Photo-sensitized decomposition of methyl alcohol in the presence of p-benzoquinone has been investigated by electron spin resonance method at a frozen state. Four kinds of ESR spectrum were distinguished ; these were CH₂OH, CHO, CH₃ and probably p-benzosemiquinone radical. Inspection of the developing pattern of these spectra has led to a result that CHO and CH₃ radicals are secondarily produced rather than photoprimarily. The methyl radical was found to be less stable compared with the other radicals. The decay of methyl radical was investigated and found to obey the second order rate law. Photo-sensitized decomposition of ethyl alcohol was investigated additionally.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 15 (7), 932-935, 1967

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390282679150161280
• NII論文ID: 110003620261
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.15.932
• ISSN: 13475223
• ISSN: 00092363
• NDL書誌ID: 8509134
• PubMed: 4296200
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8509134
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/15/7/15_7_932/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1969050974
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可