Anodic oxidation of 2- and 4'-substituted benzenesulfenanilides. A new method of synthesis of 2,7-disubstituted phenazines.

• 佐用 博照

• 森 浩一

• 植田 理子

抄録

Anodic oxidations of benzenesulfenanilides (4'-OMe (I), 4'-Me (II), 4'-Cl (III), 4'-H (IV) ) and 2-nitrobenzenesulfenanilides (4'-OMe (V), 4'-Me (VI), 4'-Cl (VII), 4'-H (VIII) ) were carried out in acetonitrile containing 0.1 M NaClO₄. electrolyses of I, II, V, VI, and VII gave the corresponding 2, 7-disubstituted phenazines, whereas those of III, IV, and VIII did not. The R-N. intermediates are suggested for the formation of the phenazines.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 25 (3), 525-527, 1977

  公益社団法人 日本薬学会

キーワード

• 2, 7-disubstituted phenazines

詳細情報

• CRID: 1390001204171061248
• NII論文ID: 110003622441
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.25.525
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/25/3/25_3_525/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1978031425
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可