Synthesis of 1-Benzometalloles Containing Group 14,15,and 16 Heavier Elements via a Common Dilithiostyrene Intermediate

被引用文献3件
  • 栗田 城治
    Faculty of Pharmaceutical Sciences, Hokuriku University
  • 石井 誠
    Faculty of Pharmaceutical Sciences, Hokuriku University
  • 安池 修之
    Faculty of Pharmaceutical Sciences, Hokuriku University
  • 土屋 隆
    Faculty of Pharmaceutical Sciences, Hokuriku University

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抄録

The Group 14 (Si, Ge, and Sn), Group 15 (P, As, Sb, and Bi), and Group 16 (Se and Te) 2-trimethylsilyl-1-benzometalloles (7) were prepared by the reaction of the corresponding metal reagents with β, o-dilithio-β-trimethyl-silylstyrene intermediate (6), which was derived from phenylacetylene or o-bromoiodobenzene via three steps. The trimethylsilyl group in 7 could be readily removed by treatment with tetrabutylammonium fluoride to give the C-unsubstituted 1-banzometalloles (10).

収録刊行物

  • Chem. Pharm. Bull.

    Chem. Pharm. Bull. 42 1437-1441, 1994

    公益社団法人日本薬学会

被引用文献 (3)*注記

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詳細情報 詳細情報について

  • CRID
    1574231877091651072
  • NII論文ID
    110003631161
  • NII書誌ID
    AA00602100
  • ISSN
    00092363
  • 本文言語コード
    en
  • データソース種別
    • CiNii Articles

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