The Chemistry of Indoles. XVI. A Convenient Synthesis of Substituted Indoles carrying a Hydroxy Group, a Halogeno Group, or a Carbon Side Chain at the 4-Position via 4-Indolediazonium Salts and a Total Synthesis of (±)-6, 7-Secoagroclavine
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- タイトル別名
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- The chemistry of indoles. XVI. A convenient synthesis of substituted indoles carrying a hydroxy group, a halogeno group, or a carbon side chain at the 4-position via 4-indolediazonium salts and a total synthesis of (.+-.)-6,7-secoagroclavine.
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Various 4-indolediazonium salts were prepared for the first time by the diazotization of 4-aminoindole derivatives. They underwent various reactions parallel to those of general arene diazonium salts, and were found to be suitable intermediates for the preparation of substituted indoles carrying a hydroxy, halogeno, or cyano group at the 4-position. Attempts to introduce various carbon side chains into the 4-iodoindole derivatives gave satisfactory results and a key intermediate, 4-(3-hydroxy) 3-methyl-1-buten-1-yl) indole, for the synthesis of (±)-6, 7-secoagroclavine was also prepared.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 29 (11), 3145-3157, 1981
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390001204166661120
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- NII論文ID
- 110003633554
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- NII書誌ID
- AA00602100
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- COI
- 1:CAS:528:DyaL38Xhs1aqu7Y%3D
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- ISSN
- 13475223
- 00092363
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- IRDB
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- CiNii Articles
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- 使用不可