Influence of the Conformation of Methoxy-(2-naphthyl)acetates (2NMA Esters) on Their Chemical Reactions.

• FUKUYOSHI Shu-ichi

• OOI Takashi

• KUSUMI Takenori

抄録

An SN2 reaction (NaI) of 1, 7-di(methanesulfoxyl)heptadien-4-yl methoxy-(2-naphthyl)acetate and a tributyltin hydride reduction of 1, 7-diiodo-4-yl methoxy-(2-naphthyl)acetate (2NMA) is crucial for determination of the absolute configuration of secondary alcohols.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 48 (8), 1208-1210, 2000

  公益社団法人 日本薬学会

キーワード

• 2NMA
• chiral anisotropic reagent
• conformation
• steric effect

詳細情報

• CRID: 1390282679136738816
• NII論文ID: 130003948163
• NII論文ID: 110003635629
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.48.1208
• ISSN: 13475223
• ISSN: 00092363
• NDL書誌ID: 5431847
• PubMed: 10959589
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5431847
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/48/8/48_8_1208/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可