金属イオン {M} -有機試薬 {R} 反応を用いる光分析法

• 森 逸男

  大阪薬科大学第II分析化学教室

書誌事項

タイトル別名

• Photometric Analysis with Reaction between Metal Ion {M} and Organic Reagent {R}
• キンゾク イオン M ユウキ シヤク R ハンノウ オ モチイル コウブンセキホウ

抄録

Firstly, the syntheses of various organic reagents {R} containing such xanthene derivatives as O-hydroxyhydro-quinonephthalein (QnPh), and 3,4,5,6-tetrahydroxyfluoran (gallein, Gall) were studied. Secondarily, the coexisting effects of surfactant (cationic-, anionic-, amphoteric- and nonionic-surfactants alone or combination) on the coloring or fluorescence reactions between various {R} such as xanthene derivatives, aromatic amines and various metal ions {M} such as bismuth (III), tin (IV), iron (III), molybdenum (VI), uranium (VI), cobalt (II), aluminum (III), etc. were systematically investigated. Thirdly, numerous simple and sensitive photometric analyses (spectrophotometry and fluorophotometry) for various {M} and organic compounds {Org} such as biological samples, and pharmaceutical preparations by formation reactions of {R-M} binary or {(R-M)-Org} ternary complexes were established in the coexistence of surfactant alone or combination.

収録刊行物

• 薬学雑誌

  薬学雑誌 121 (10), 707-731, 2001-10-01

  公益社団法人 日本薬学会

キーワード

• organic reagents
• metal ion
• surfactants
• associated complexes
• photometric analysis
• pharmaceuticals and biologicals

詳細情報

• CRID: 1390001206128508032
• NII論文ID: 110003648479
• NII書誌ID: AN00284903
• DOI: 10.1248/yakushi.121.707
• COI: 1:CAS:528:DC%2BD3MXnt1GqtL0%3D
• ISSN: 13475231
• ISSN: 00316903
• NDL書誌ID: 5923065
• PubMed: 11676174
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5923065
• Web Site: https://www.jstage.jst.go.jp/article/yakushi/121/10/121_10_707/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可