Palladium-Catalyzed Allylation of Acidic and Less Nucleophilic Anilines Using Allylic Alcohols Directly

• Hsu Yi-Chun

  Graduate Institute of Pharmaceutical Sciences, Kaohsiung Medical University

• Gan Kim-Hong

  Graduate Institute of Pharmaceutical Sciences, Kaohsiung Medical University

• Yang Shyh-Chyun

  Graduate Institute of Pharmaceutical Sciences, Kaohsiung Medical University

抄録

The direct activation of C–O bonds in allylic alcohols by palladium complexes has been accelerated by carrying out the reactions in the presence of titanium(IV) isoproxide and 4 Å molecular sieves. The acidic and less nucleophilic anilines such as diphenylamine, phenothiazine, 4-cyanoaniline, and nitroanilines are efficiently allylated under palladium catalysis using allylic alcohols as allylating reagents.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 53 (10), 1266-1269, 2005

  公益社団法人 日本薬学会

キーワード

• palladium-catalyzed
• allylation
• acidic anilines
• C–N bond formation

詳細情報

• CRID: 1390282679146150784
• NII論文ID: 110003666257
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.53.1266
• ISSN: 13475223
• ISSN: 00092363
• NDL書誌ID: 7449247
• PubMed: 16204982
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7449247
• Web Site: http://www.jstage.jst.go.jp/article/cpb/53/10/53_10_1266/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可