Deep levels studies of N-free and N-doped GaP grown by TDM-CVP.

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The energies and densities of deep levels in N-free and N-doped GaP LED depend on the applied phosphorus pressure during epitaxial growth. Especially, the deep level in N-free GaP located at ECET=0.65 eV strongly affects the brightness of emission and has close correlation with the shallow donor concentration in the n layer. The deep levels in N-doped GaP are complicated and their energies change according to the phosphorus pressure. Some of the deep levels in N-doped GaP are proposed for the complex of nitrogen.

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