Influence of Boundaries on the Phase Transition Point in Ferroelectric Smectics

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The influence of boundary conditions on the smectic A-C* phase transition has been studied.<BR>From a consideration of the free energy under the anchoring condition with planar orientation of moelcules on two boundaries, it is shown that the phase transition temperature from the smectic-A to smectic-C phases decreases with decreasing layer thickness. This is confirmed by experiment.

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