Formation of Ordered Rod-like Clusters of Iodine on H-Terminated Si(111) Surfaces During Immersion in Concentrated HI Solutions.

DOI Web Site Web Site Web Site 被引用文献1件 参考文献64件
  • Imanishi Akihito
    Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan
  • Ishida Masaki
    Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan
  • Zhou Xiaowen
    Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan
  • Nakato Yoshihiro
    Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

この論文をさがす

抄録

Iodine adsorption (or reaction) on atomically-flat H-terminated Si(111) surfaces in 7.1 M HI and 7.1 M HI+0.05 M I2 was investigated by X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). XPS measurements showed that iodine was adsorbed gradually with time when immersed in 7.1 M HI, and rapidly and in a larger quantity when immersed in 7.1 M HI/0.05 M I2. AFM inspection showed that circular dot-like clusters were formed initially in both the HI and HI/I2 solutions. However, for the case of 7.1 M HI solution, dot-like clusters, located near steps, grew with time only in particular directions of threefold symmetry of Si(111), resulting in ordered wire-like clusters. For the case of HI/I2 solution, the circular dot-like clusters were distributed randomly on terraces and steps even after prolonged immersion, with no formation of any ordered clusters.

収録刊行物

被引用文献 (1)*注記

もっと見る

参考文献 (64)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ