3D04 有機金属錯体のディスコティック液晶 (74^*) : 高速伝導性ビス [オクタキス (3, 4-ジアルコキシフェノキシ) フタロシアニナート] Lu (III) 錯体の合成およびその液晶性と配向性に及ぼす鎖長の効果(2004年日本液晶学会討論会)

• 向井 秀知

  信州大・繊維

• 初阪 一輝

  信州大・繊維

• 太田 和親

  信州大・繊維

書誌事項

タイトル別名

• 3D04 Discotic Liquid Crystals of Organic Metal Complexes (74) : Synthesis of Highly Conductive Bis [octakis (3, 4-dialkoxyphenoxy) phthalocyaninato] lutetium (III) complexes to Investigate Effect of the Chain Length on Mesomorphism and Alignment Properties

抄録

The lutetium sandwich complexes (n=8-16) in the title were synthesized to obtain discotic liquid crystals showing both spontaneous homeotropic alignment and high mobility. Recycling HPLC effectively separated the double-deckers and triple-deckers. The amount of triple-deckers was too short to study their physical properties. The double-deckers show one Col_h, two Cub and one Col_<tet> mesophases for n≦13, and a Col_r mesophase for n≧14 instead of the Col_h mesophase. Interestingly, the Col_<tet> mesophases for n≧10 exhibit spontaneous homeotropic alignment.

収録刊行物

• 日本液晶学会討論会講演予稿集

  日本液晶学会討論会講演予稿集 (2004), 86-87, 2004-09-26

  日本液晶学会

詳細情報

• CRID: 1574231876690089088
• NII論文ID: 110004615248
• NII書誌ID: AA11639022
• 本文言語コード: ja
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