Theoretical Studies on the Dielectric Breakdown of the SiO_2 Thin Films

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Electronic structures of oxygen deficiency in the SiO_2 thin film are theoretically studied by using the cluster models of Si_2O_7H_6 and Si_2O_6H_6 in order to reveal the mechanism of dielectric breakdown observed in the thin films. It is found that the oxygen deficiency induces electron traps rather than hole traps. Furthermore, F^- ions captured through the HF treatments are considered to be a key to introduce the oxygen deficiency in the SiO_2 thin films.

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