Analysis of Mechanical Behavior of Polymers Using Molecular Chain Network Model
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- SHINOZAKI Akira
- Tokyo Institute of Technology, Graduate School of Science and Engineering, Department of Mechanical and Control Engineering
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- INOUE Hirotsugu
- Tokyo Institute of Technology, Graduate School of Science and Engineering, Department of Mechanical and Control Engineering
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- KISHIMOTO Kikuo
- Tokyo Institute of Technology, Graduate School of Science and Engineering, Department of Mechanical and Control Engineering
Bibliographic Information
- Other Title
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- Analysis of Mechanical Behavior of Polymers Using Molecular Chain Network Model (Effects of Molecular Weight Distribution and Ultra-Violet Degradation)
- (Effects of Molecular Weight Distribution and Ultra-Violet Degradation)
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Abstract
A computational procedure for analyzing the deformation and fracture of solid polymers is developed based on a molecular chain model. In the model, the polymer solid is represented by a network of nonlinear elastic chains. Cellular automata modeling is employed to generate the network of polymer chains. Van der Waals and viscous forces acting on the chains are taken into account and are approximated to act at the nodal points of the network. A stiffness equation is derived by employing the principle of virtual work, in which geometrical nonlinearity due to a large deformation is considered. Slippage and scission of chains are also taken into consideration. The effects of molecular weight distribution and molecular chain scission due to UV-degradation are discussed.
Journal
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- JSME International Journal Series A
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JSME International Journal Series A 49 (4), 503-512, 2006
The Japan Society of Mechanical Engineers
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Keywords
Details 詳細情報について
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- CRID
- 1390001206494681472
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- NII Article ID
- 110004820916
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- NII Book ID
- AA11179396
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- COI
- 1:CAS:528:DC%2BD2sXktlGquw%3D%3D
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- ISSN
- 13475363
- 13447912
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- NDL BIB ID
- 8082295
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed