Investigation of Selective Mono-deallylation of O,O'-Diallylcatechols and 3-Methylene-1,5-benzodioxepanes
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- Hayashida Maiko
- Faculty of Pharmaceutical Sciences, Tokyo University of Science (RIKADAI)
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- Ishizaki Miyuki
- Faculty of Pharmaceutical Sciences, Josai International University (JIU)
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- Hara Hiroshi
- Faculty of Pharmaceutical Sciences, Tokyo University of Science (RIKADAI)
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抄録
Selective mono-deallylation of O,O′-diallylcatechols using 10% Pd/C was investigated to give the correspond-ing allylphenols. A similar reaction of 3-methylene-1,5-benzodioxepanes afforded O-methacryl catecohols. When substrates bearing various substituents on the benzene ring were subjected to the reaction, regioselective cleavage of an ether bond occurred at the side of para position to an electron-withdrawing group on the aromatic ring. On the other hand, an electron-donating group did not cause any selectivity.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 54 (9), 1299-1303, 2006
公益社団法人 日本薬学会
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詳細情報
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- CRID
- 1390001204168828032
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- NII論文ID
- 110004836452
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- NII書誌ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- NDL書誌ID
- 8026922
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可