Dirhodium(II) Tetrakis(perfluorobutyrate)-Catalyzed 1,4-Hydrosilylation of .ALPHA.,.BETA.-Unsaturated Carbonyl Compounds

• Anada Masahiro

  Faculty of Pharmaceutical Sciences, Hokkaido University

• Tanaka Masahiko

  Faculty of Pharmaceutical Sciences, Hokkaido University

• Suzuki Kanami

  Faculty of Pharmaceutical Sciences, Hokkaido University

• Nambu Hisanori

  Faculty of Pharmaceutical Sciences, Hokkaido University

• Hashimoto Shunichi

  Faculty of Pharmaceutical Sciences, Hokkaido University

Abstract

The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of α,β-unsaturated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh₂(pfb)₄, proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields.

Journal

• Chemical and Pharmaceutical Bulletin

  Chemical and Pharmaceutical Bulletin 54 (11), 1622-1623, 2006

  The Pharmaceutical Society of Japan

Keywords

• dirhodium(II) complex
• 1,4-hydrosilylation
• silyl enol ether
• α,β-enone

Details

• CRID: 1390282679148082688
• NII Article ID: 110004836491
• NII Book ID: AA00602100
• DOI: 10.1248/cpb.54.1622
• ISSN: 13475223
• ISSN: 00092363
• HANDLE: 2115/17095
• Web Site: http://www.jstage.jst.go.jp/article/cpb/54/11/54_11_1622/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • IRDB
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed