Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids

• 初井 敏英

  九州大学機能物質科学研究所

• Hirata Narukuni

  Interdisciplinary Graduate School of Engineering Sciences, Kyushu University

• 竹下 齊

  九州大学機能物質科学研究所

書誌事項

タイトル別名

• Addition Reaction of 2 Pyrone 5 carboxy

抄録

Methyl 2-pyrone-5-carboxylate reacted with α-terpinene site- and regio-selectively to give tricycle lactones at 110℃. At a higher temperature, decarboxylation and subsequent intramolecular cycloaddition took place to afford a triene and a tetracyclic ester. A triene diester and hydroxy diesters were synthesized from the lactones. Attempted conversion of them to eudesmanoids are described.

収録刊行物

• 九州大学機能物質科学研究所報告

  九州大学機能物質科学研究所報告 10 (1), 35-39, 1996-11-12

  九州大学機能物質科学研究所

詳細情報

• CRID: 1390009224835569792
• NII論文ID: 110006177499
• NII書誌ID: AN10060378
• ISSN: 09143793
• DOI: 10.15017/6690
• HANDLE: 2324/6690
• NDL書誌ID: 4085346
• Web Site: http://id.ndl.go.jp/bib/4085346
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4085346
• 本文言語コード: en
• データソース種別:
  • JaLC
  • IRDB
  • NDL
  • CiNii Articles
• 抄録ライセンスフラグ: 使用可