Effect of Strain in Epitaxially Grown SrRuO<sub>3</sub>Thin Films on Crystal Structure and Electric Properties

  • Takahashi Kenji
    Department of Innovative and Engineered Materials, Tokyo Institute of Technology, G1-405, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
  • Oikawa Takahiro
    Department of Innovative and Engineered Materials, Tokyo Institute of Technology, G1-405, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
  • Saito Keisuke
    Application Laboratory, Analytical Division, Philips Japan, Ltd., 35-1, Sagamiono 7-chome, Sagamihara, Kanagawa 228-8505, Japan
  • Kaneko Satoru
    Kanagawa Industrial Technology Research Institute, 705-1 Shimoimaizumi, Ebina, Kanagawa 243-0435, Japan
  • Fujisawa Hironori
    Department of Electrical, Electronic and Computer Engineering, Graduate School of Engineering, Himeji Institute of Technology, 2167 Shosha, Himeji, Hyogo 671-2201, Japan
  • Shimizu Masaru
    Department of Electrical, Electronic and Computer Engineering, Graduate School of Engineering, Himeji Institute of Technology, 2167 Shosha, Himeji, Hyogo 671-2201, Japan
  • Funakubo Hiroshi
    Department of Innovative and Engineered Materials, Tokyo Institute of Technology, G1-405, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan

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タイトル別名
  • Effect of Strain in Epitaxially Grown SrRuO3 Thin Films on Crystal Structure and Electric Properties.

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SrRuO3 thin films were epitaxially grown on (001)SrTiO3 and (001) [(LaAlO3)0.3-(SrAl0.5Ta0.5O3)0.7] (LSAT) substrates by rf magnetron sputter deposition and metalorganic chemical vapor deposition (MOCVD), and their crystal structure, electric property and thermal stability were investigated. SrRuO3 films prepared by MOCVD (MOCVD-SrRuO3 films) had almost the same volume of unit cell as that of the single crystal, while those prepared by rf magnetron sputter deposition (sputter-SrRuO3 films) had a larger volume. This large volume of the unit cell of sputter-SrRuO3 films decreased by the post annealing up to 830°C but did not reach that of the single crystal one. Temperature dependence of the resistivity of MOCVD-SrRuO3 films was in good agreement with that of the single crystal, which corresponds to metallic behavior, while that of sputter-SrRuO3 films showed semiconductor-like behavior below 120 K.

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