A Study on the Properties of Adhesion and Durability of Dental Adhesive : Part 2 Adhesion and Durability of Various Functional Monomers

歯科用接着材の接着性ならびに耐久性についての研究 : 第2報種々な機能性モノマーの歯質接着性および耐久性 [in Japanese] A Study on the Properties of Adhesion and Durability of Dental Adhesive : Part 2 Adhesion and Durability of Various Functional Monomers [in Japanese]

- 押川亮宏 OSHIKAWA Akihiro
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College
- 花岡孝治 HANAOKA Koji
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College
- 海老原敬 EBIHARA Kei
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College
- 倉田茂昭 KURATA Shigeaki
- 神奈川歯科大学生体材料器械学講座 Department of Biomaterials and Devices, Kanagawa Dental College
- 楳本貢三 UMEMOTO Kozo
- 神奈川歯科大学生体材料器械学講座 Department of Biomaterials and Devices, Kanagawa Dental College
- 近藤行成 KONDO Yukishige
- 東京理科大学工学部工業化学科 Department of Industrial Chemistry, Tokyo University of Science
- 好野則夫 YOSHINO Norio
- 東京理科大学工学部工業化学科 Department of Industrial Chemistry, Tokyo University of Science
- 寺中敏夫 TERANAKA Toshio
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College

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- 押川亮宏 OSHIKAWA Akihiro
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College
- 花岡孝治 HANAOKA Koji
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College
- 海老原敬 EBIHARA Kei
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College
- 倉田茂昭 KURATA Shigeaki
- 神奈川歯科大学生体材料器械学講座 Department of Biomaterials and Devices, Kanagawa Dental College
- 楳本貢三 UMEMOTO Kozo
- 神奈川歯科大学生体材料器械学講座 Department of Biomaterials and Devices, Kanagawa Dental College
- 近藤行成 KONDO Yukishige
- 東京理科大学工学部工業化学科 Department of Industrial Chemistry, Tokyo University of Science
- 好野則夫 YOSHINO Norio
- 東京理科大学工学部工業化学科 Department of Industrial Chemistry, Tokyo University of Science
- 寺中敏夫 TERANAKA Toshio
- 神奈川歯科大学口腔治療学講座保存修復学分野 Division of Restorative Dentistry, Department of Oral Medicine, Kanagawa Dental College

Abstract

接着修復において接着層形成時および形成後に介在する水は接着を左右する重要な因子である.接着層の耐久性向上を目的として,4-META(ME)またはMDPを含むHEMA-エタノールベース試作セルフエッチングプライマーに2種フッ素化合物(sodium1-[(4-heptadecafluorooctyl)phenyl]-1-butyl-phenyl phosphate:FH3,2,2,2-trifluoroethyl methacrylate:3FMA)を添加して,1年水中保管ならびにサーマル試験後の接着強さを測定し,その有効性を評価した.エナメル質接着では,両接着性モノマーともフッ素化合物添加による有効性は認められなかった.一方,象牙質接着では,FH3添加群では有効性は認められなかったが,3FMAを0.5〜5wt%添加したME含有プライマーでは,経時的に安定した接着が維持された.SEM観察では,全ての試料で明瞭な樹脂含浸層は観察されなかった.以上の結果から,3FMAはME含有セルフエッチングプライマーの象牙質接着の耐久性を向上させる有望なモノマーであることが示唆された.

In adhesive restoration, water intervention during or after the formation of the adhesive layer is an important factor having a decisive influence on adhesion. To improve the durability of the adhesive layer, two kinds of fluorine compounds: (sodium1-[(4-heptadecafluorooctyl)phenyl]-1-butyl-phenyl phosphate : FH3, and 2,2,2-trifluoroethyl methacrylate : 3FMA), were added to experimental selfetching primers on the HEMA-ethanol base containing 4-META(ME) or MDP, and measured bond strength was measured after one-year water storage or a thermal cycling test to evaluate the efficiency of the fluorine compounds. For adhesion to enamel, the addition of fluorine compounds to either adhesive monomer showed no effect. In contrast, for adhesion to dentine, the ME-containing primer added to 3FMA (0.5〜5% by weight) retained stable adhesive bonding over time, while the addition of FH3 had no effect. No distinct resin hybrid-layer was observed in any specimen on SEM observation. The results suggested that 3FMA would be a promising monomer to improve the durability of dentin adhesion of self-etching primers containing ME.

Journal

The Journal of the Japanese Society for Dental Materials and Devices

The Journal of the Japanese Society for Dental Materials and Devices 27(3), 246-255, 2008

The Japanese Society for Dental Materials and Devices

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