Effect of Structural Parameters on Superconductivity in Fluorine-Free LnFeAsO<SUB>1−<I>y</I></SUB> (Ln = La, Nd)

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  • Effect of structural parameters on superconductivity in fluorine-free LnFeAsO1-y (Ln = La, Nd)
  • Effect of Structural Parameters on Superconductivity in Fluorine-Free LnFeAsO<sub>1-<i>y</i></sub> (Ln = La, Nd)

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Abstract

The crystal structure of LnFeAsO1−y (Ln = La, Nd) has been studied by the powder neutron diffraction technique. The superconducting phase diagram of NdFeAsO1−y is established as a function of oxygen content which is determined by Rietveld refinement. The small As–Fe bond length suggests that As and Fe atoms are connected covalently. FeAs4-tetrahedrons transform toward a regular shape with increasing oxygen deficiency. Superconducting transition temperatures seem to attain maximum values for regular FeAs4-tetrahedrons.

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