Electrical properties of ternary metal-rich telluride Pd_2NiTe_2

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Abstract

A ternary metal-rich telluride Pd<sub>2</sub>NiTe<sub>2</sub> has been prepared by the solid-state reaction. This compound crystallizes in the orthorhombic K<sub>2</sub>ZnO<sub>2</sub>-type structure with space group <i>Ibam</i>. In this structure, the Ni atom is tetrahedrally coordinated and the NiTe<sub>4</sub> tetrahedra share edges forming one-dimensional chains with short Ni-Ni bondings along the <i>c</i>-axis. Through magnetic susceptibility, specific heat, and electrical resistivity measurements, this compound shows Pauli paramagnetism and metallic electrical conductivity. The electronic structure calculation of Pd<sub>2</sub>NiTe<sub>2</sub> suggests that its electrical conductivity is a three-dimensional one, which is caused by conduction bands originated from <i>d</i> orbitals of Pd and Ni and <i>p</i> orbitals of Te.

Journal

  • Journal of the Ceramic Society of Japan

    Journal of the Ceramic Society of Japan 117(1361), 27-31, 2009-01-01

    The Ceramic Society of Japan

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Codes

  • NII Article ID (NAID)
    110007026734
  • NII NACSIS-CAT ID (NCID)
    AA12229489
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    18820743
  • NDL Article ID
    9751594
  • NDL Source Classification
    ZP9(科学技術--化学・化学工業--無機化学・無機化学工業--セラミックス・窯業)
  • NDL Call No.
    Z78-A504
  • Data Source
    CJP  NDL  NII-ELS  J-STAGE 
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