14. アルケンのソノケミカル活性化

• 藤田 光恵

  滋賀医大化

• 木村 隆英

  滋賀医大化

• 宗宮 創

  滋賀医大化

• 安藤 喬志

  滋賀医大化

書誌事項

タイトル別名

• 14. Sonochemical Activation of Alkenes

抄録

Extensive studies in our laboratory have revealed that the sonochemical switching from ionic to radial in the nature of the reaction of lead tetraacetate with styrenes in acetic acid stems from the possible sonochemical excitation of styrenes in the cavitation process. We have found that the yields of the radical reactions of substituted styrenes show a linear relationship with their vapor pressures. In order to establish the hypothesis that the sonochemical activation depends on the vapor pressures of the substrates under the particular reaction conditions, the sonochemical activation of various alkenes including substituted styrenes was analyzed by determining the decomposition of pyrocatechol, a radical scavenger, in an acetic acid solution in the absence of lead tetraacetate. Results will be discussed from the viewpoint mentioned above.

収録刊行物

• ソノケミストリー討論会講演論文集

  ソノケミストリー討論会講演論文集 8 (0), 57-59, 1999

  日本ソノケミストリー学会

詳細情報

• CRID: 1390282681029281664
• NII論文ID: 110009710098
• DOI: 10.20577/pamjss.8.0_57
• ISSN: 24241512
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可