Novel syntheses of 1-hydroxy-6- and -5-nitroindole-3-carbaldehydes, and their derivatives as daikon-phytoalexin analogs

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金沢大学大学院自然科学研究科生理活性物質科学

金沢大学薬学部

1-Hydroxy-6- and -5-nitroindole-3-carbaldehydes are prepared for the first time from 1-methoxy-6- and -5-nitroindole-3-carbaldehydes, respectively, based on the discovery of novel methyl ether cleavage reaction. Utilizing them as common synthetic intermediates, syntheses of several daikon-phytoalexin analogs are achieved.

収録刊行物

  • Heterocycles

    Heterocycles 63 (7), 1601-1611, 2004-07-01

    日本複素環化学研究所

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